Modern nucleophilic aromatic substitution /
Terrier, François.
Modern nucleophilic aromatic substitution / François Terrier. - 1 online resource (xiii, 472 pages) : illustrations
Includes bibliographical references and index.
The SnAr Reactions: Mechanistic Aspects -- Structure and Reactivity of Anionic [alpha]-Complexes -- The Superelectrophilic Dimension in SnAr and Related [alpha]-Complexation Processes -- Synthetic Aspects of Intermolecular SnAr Reactions -- Intramolecular SnAr Reactions -- Nucleophilic Aromatic Substitutions of Hydrogen -- Other SnAr Substitution Pathways.
This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes.
9783527656141 3527656146 9783527656172 3527656170 9783527656165 9783527656158 3527656154 3527656162
016285206 Uk
Aromatic compounds--Synthesis.
Aromatic compounds.
Organic compounds--Synthesis.
Science.
SCIENCE--Chemistry--Organic.
Aromatic compounds--Synthesis.
Electronic books.
QD262 / .T384 2013
547.2
Modern nucleophilic aromatic substitution / François Terrier. - 1 online resource (xiii, 472 pages) : illustrations
Includes bibliographical references and index.
The SnAr Reactions: Mechanistic Aspects -- Structure and Reactivity of Anionic [alpha]-Complexes -- The Superelectrophilic Dimension in SnAr and Related [alpha]-Complexation Processes -- Synthetic Aspects of Intermolecular SnAr Reactions -- Intramolecular SnAr Reactions -- Nucleophilic Aromatic Substitutions of Hydrogen -- Other SnAr Substitution Pathways.
This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes.
9783527656141 3527656146 9783527656172 3527656170 9783527656165 9783527656158 3527656154 3527656162
016285206 Uk
Aromatic compounds--Synthesis.
Aromatic compounds.
Organic compounds--Synthesis.
Science.
SCIENCE--Chemistry--Organic.
Aromatic compounds--Synthesis.
Electronic books.
QD262 / .T384 2013
547.2