TY - BOOK AU - Terrier,François TI - Modern nucleophilic aromatic substitution SN - 9783527656141 AV - QD262 .T384 2013 U1 - 547.2 PY - 2013///] CY - Weinheim, Hoboken PB - Wiley-VCH Verlag GmbH & Co. KGaA KW - Aromatic compounds KW - Synthesis KW - Organic compounds KW - Science KW - SCIENCE KW - Chemistry KW - Organic KW - bisacsh KW - fast KW - Electronic books N1 - Includes bibliographical references and index; The SnAr Reactions: Mechanistic Aspects --; Structure and Reactivity of Anionic [alpha]-Complexes --; The Superelectrophilic Dimension in SnAr and Related [alpha]-Complexation Processes --; Synthetic Aspects of Intermolecular SnAr Reactions --; Intramolecular SnAr Reactions --; Nucleophilic Aromatic Substitutions of Hydrogen --; Other SnAr Substitution Pathways N2 - This book provides a comprehensive overview of nucleophilic aromatic substitutions, focusing on the mechanistic and synthetic features that govern these reactions. The first chapter presents a detailed mechanistic analysis of the factors determining the feasibility of SNAr substitutions, providing decisive information to predict regioselectivity of many reactions and to define the conditions for concerted SNAr processes. Reflecting the key role played by these species as intermediates in most SNAr reactions, chapter 2 then discusses the chemistry of anionic sigma-complexes UR - http://onlinelibrary.wiley.com/book/10.1002/9783527656141 ER -